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I *think* you can address that by putting the fuel selector to OFF. I don't know if the interconnect between the right and left tanks will continue to feed the tank that is overflowing (not really leaking).
Good thoughts here and that is correct. You can stop inter tank fuel transfer through the fuel selector while in OFF, RIGHT or LEFT.
Here is a photo of a 182 fuel valve opened up. The body is upside down while on the bench.
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The vent interconnect will crossfeed fuel up to a certain point. Certainly, with partial tanks and parked on an unlevel spot, the fuel has the potential to transfer between tanks.
The fuel vent is nothing more than a flapper valve, hinged at the top. Even so, it has a pinhole to always allow some venting. To access it, you need to pull the outboard fuel cap on the left wing. As Tom said, leaking fuel is quite common.
McFarlane Aviation makes and sells a fuel vent line for the 182 that has a "trap" in it that helps stop some of the fuel venting problems. I have one installed and it works quite well but is not a 100% solution.
https://www.mcfarlaneaviation.com/produ ... ent-lines/One more thought to the OP. You don't mention whether this leak is on the ground or in flight. If the vent line is not properly adjusted in relation to the left wing strut, you could be pressurizing the fuel tanks and causing excessive venting. The fuel vent needs to be adjusted vertically to stick down below the wing strut 0.19". Yes, it's that precise.